Part of JINC-04 — s-Block Elements & Hydrogen

Hydrogen Peroxide — Structure and Reactions

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H2O2 has open-book (non-planar) structure. O is in -1 oxidation state. Dihedral angle: 111.5 degrees (gas), 90.2 degrees (solid). As oxidiser: H2O2 + 2KI → I2 + 2KOH; H2O2 + 2Fe2+Fe^{2+} + 2H+H^+ → 2Fe3+Fe^{3+} + 2H2O; PbS (black) + 4H2O2 → PbSO4 (white) + 4H2O (restores old paintings). As reducer: 2MnO4MnO4^- + 5H2O2 + 6H+H^+ → 2Mn2+Mn^{2+} + 5O2 + 8H2O; Cl2 + H2O2 → 2HCl + O2. Volume strength: "x volume" means 1 mL of H2O2 solution gives x mL of O2 at STP. Formula: Volume strength = 11.2 x Molarity = 5.6 x Normality. Stored in dark wax-coated bottles (light and rough surfaces catalyse decomposition). MnO2, Pt, and catalase enzyme decompose H2O2.

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