Hess's law: is path-independent. Three calculation methods: (1) Formation enthalpies: = sum(n* products) - sum(n* reactants). Elements in standard state have = 0. (2) Bond energies: = sum(BE bonds broken) - sum(BE bonds formed). Breaking bonds is endothermic (+), forming is exothermic (-). (3) Combustion enthalpies: = sum(n* reactants) - sum(n* products). Note the reversal compared to formation! Common error: mixing up the sign convention between formation (products - reactants) and bond energy (reactants - products for bonds).
Part of JPC-04 — Chemical Thermodynamics: Enthalpy, Entropy & Gibbs
Hess's Law — Three Approaches
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