Part of JPC-04 — Chemical Thermodynamics: Enthalpy, Entropy & Gibbs

Hess's Law — Three Approaches

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Hess's law: deltaHdelta_H is path-independent. Three calculation methods: (1) Formation enthalpies: deltaHdelta_H = sum(n*deltaHfdelta_{Hf} products) - sum(n*deltaHfdelta_{Hf} reactants). Elements in standard state have deltaHfdelta_{Hf} = 0. (2) Bond energies: deltaHdelta_H = sum(BE bonds broken) - sum(BE bonds formed). Breaking bonds is endothermic (+), forming is exothermic (-). (3) Combustion enthalpies: deltaHdelta_H = sum(n*deltaHcdelta_{Hc} reactants) - sum(n*deltaHcdelta_{Hc} products). Note the reversal compared to formation! Common error: mixing up the sign convention between formation (products - reactants) and bond energy (reactants - products for bonds).

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