| Term | Definition |
|---|---|
| Contact process | Industrial 4-step method for manufacturing H2SO4 using V2O5 catalyst at 450°C |
| Oleum (fuming H2SO4) | H2S2O7 (pyrosulfuric acid) — formed when SO3 is dissolved in concentrated H2SO4 |
| Acid mist | Fine aerosol of H2SO4 droplets formed when SO3 reacts directly with water — too fine to condense |
| Chalcogens | Group 16 elements: O, S, Se, Te, Po — named from Greek "chalcos" (copper ore) |
| Halogens | Group 17 elements: F, Cl, Br, I, At — named from Greek "hals" (salt) + "gen" (producer) |
| Noble gases | Group 18 elements: He, Ne, Ar, Kr, Xe, Rn — very low reactivity, complete valence shells |
| Interhalogen compounds | Compounds formed between two different halogens. Formula: ABn (n = 1, 3, 5, 7) |
| Hybridization | Mixing of atomic orbitals to form new hybrid orbitals of equivalent energy for bonding |
| sp3d hybridization | Mixing of 1s + 3p + 1d orbital → 5 hybrid orbitals → TBP electron geometry |
| sp3d2 hybridization | Mixing of 1s + 3p + 2d orbitals → 6 hybrid orbitals → Octahedral electron geometry |
| sp3d3 hybridization | Mixing of 1s + 3p + 3d orbitals → 7 hybrid orbitals → Pentagonal bipyramidal geometry |
| VSEPR theory | Valence Shell Electron Pair Repulsion — predicts molecular shape based on electron pair repulsions |
| Diprotic acid | Acid that can donate 2 protons per molecule (e.g., H2SO4) |
| Allotropes | Different physical forms of the same element (e.g., rhombic and monoclinic sulfur) |
| Rhombic sulfur | Most stable sulfur allotrope at room temperature; consists of S8 crown-shaped rings; orthorhombic crystal |
| Clathrate compound | "Cage compound" where noble gas atoms are physically trapped in lattice of water/organic molecules without chemical bonding |
| Nascent oxygen | Highly reactive atomic oxygen [O] released by decomposition of O3 → O2 + [O] |
| Bleaching powder | CaOCl2 — mixed salt of HCl and HOCl, prepared by Cl2 + Ca(OH)2 |
| Resonance hybrid | A molecule whose actual structure is an average of two or more contributing structures (e.g., O3, SO2) |
| Sulfonating agent | Reagent that introduces -SO3H group into organic molecules (e.g., H2SO4 in aromatic sulfonation) |
| KI-starch paper | Test paper used to detect oxidizing agents (O3, Cl2); turns blue-black when I2 is liberated |
Part of INC-03 — p-Block Elements: Groups 16-18
Glossary — INC-03 Key Terms
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