Part of JTHERM-02 — Kinetic Theory of Gases

Gas Mixture Properties

by Notetube Official102 words4 views
  • id: JTHERM-02-N11
  • title: Equivalent Molar Mass and Gamma for Gas Mixtures
  • tags: mixture, molar-mass, equivalent-gamma

For a mixture of ideal gases, the equivalent molar mass is the weighted average: Mmix=(n1M1+n2M2)/(n1+n2)M_{\text{mix}} = (n_1M_1 + n_2M_2)/(n_1 + n_2). The equivalent γ\gamma is found from: ntotal/(γmix1)=n1/(γ11)+n2/(γ21)n_{\text{total}}/(\gamma_{\text{mix}} - 1) = n_1/(\gamma_1 - 1) + n_2/(\gamma_2 - 1). This comes from Cv,mix=(n1Cv1+n2Cv2)/(n1+n2)C_{v,\text{mix}} = (n_1C_{v1} + n_2C_{v2})/(n_1 + n_2) and Cp,mix=Cv,mix+RC_{p,\text{mix}} = C_{v,\text{mix}} + R. For adiabatic processes of a gas mixture, use γmix\gamma_{\text{mix}} in all formulas (PVγmix=CPV^{\gamma_{\text{mix}}} = C, etc.). These mixture formulas are frequently tested in JEE, often combined with thermodynamic process questions.

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