Part of JTHERM-01 — Thermodynamics: Laws, Processes & Engines

Free Expansion and Irreversible Processes

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  • id: JTHERM-01-N13
  • title: Free Expansion of an Ideal Gas
  • tags: free-expansion, irreversible, joule

In free expansion, a gas expands into a vacuum: W = 0 (no opposing pressure), Q = 0 (adiabatic), so ΔU=0\Delta U = 0. For ideal gas: ΔT=0\Delta T = 0. But entropy increases (irreversible). This is different from adiabatic expansion against a piston (where gas cools). Free expansion is the most extreme case of irreversibility — the gas expands without doing any useful work.

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