Photoelectric Effect
\text{Einstein's Equation:} \quad KE_{\max} = h\nu - \phi \quad [ML^2$T^{-2}$] \quad \text{(J or eV)}
\text{Stopping Potential:} \quad eV_0 = h\nu - \phi \implies V_0 = \frac{h\nu - \phi}{e} \quad [ML^2$T^{-3}A^{-1}$] \quad \text{(V)}$$
\text{Threshold Frequency:} \quad \nu_0 = \frac{\phi}{h} \quad [$T^{-1}$] \quad \text{(Hz)}
Threshold Wavelength:λ0=ϕhc[L](m)
\text{KE in terms of wavelength:} \quad KE_{\max} = hc\left(\frac{1}{\lambda} - \frac{1}{\lambda_0}\right) \quad [ML^2$T^{-2}$]
Photon Properties
\text{Photon Energy:} \quad E = h\nu = \frac{hc}{\lambda} \quad [ML^2$T^{-2}$] \quad \text{(J or eV)}
\text{Photon Momentum:} \quad p = \frac{h}{\lambda} = \frac{E}{c} = \frac{h\nu}{c} \quad [M$LT^{-1}$] \quad \text{(kg m/s)}
\text{Planck's constant:} \quad h = 6.63 \times 10^{-34} \text{ J s} \quad [ML^2$T^{-1}$]
Energy conversion:1 eV=1.6×10−19 J
de Broglie Wavelength
General:λ=mvh=ph[L](m)
From KE:λ=2m⋅KEh[L]
Electron through potential V:λ=2meeVh=V1.227 nm(electrons ONLY)
Thermal wavelength:λ=3mkTh[L](k = Boltzmann constant)
Mass ratio at same V:λ2λ1=m2m2⟹λpλe=memp≈42.8
Key Constants
| Constant | Symbol | Value | Dimensions |
|---|
| Planck's constant | h | 6.63×10−34 J s | [ML^{2}$$T^{-1}] |
| Speed of light | c | 3×108 m/s | [LT−1] |
| Electron mass | m_e | 9.1×10−31 kg | [M] |
| Proton mass | m_p | 1.67×10−27 kg | [M] |
| Electron charge | e | 1.6×10−1^{9} C | [AT] |
| Boltzmann constant | k | 1.38×10−23 J/K | [ML^{2}$$T^{-2}$$K^{-1}] |
| hc product | hc | 1240 eV·nm | useful shortcut |