Part of PC-01 — Some Basic Concepts in Chemistry

Formula & Reaction Sheet

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Core Mole Equations

n=mass (g)molar mass (g/mol)n = \frac{\text{mass (g)}}{\text{molar mass (g/mol)}}

Nparticles=n×NA=n×6.022×1023N_{\text{particles}} = n \times N_A = n \times 6.022 \times 10^{23}

VSTP=n×22.4 L/mol(0 °C, 1 atm)V_{\text{STP}} = n \times 22.4 \ \text{L/mol} \quad \text{(0 °C, 1 atm)}

Percentage Composition

% element=n×atomic massmolar mass×100\% \text{ element} = \frac{n \times \text{atomic mass}}{\text{molar mass}} \times 100

Molecular Formula from Empirical Formula

n=MrEmpirical Formula Massn = \frac{M_r}{\text{Empirical Formula Mass}}

Molecular Formula=n×Empirical Formula\text{Molecular Formula} = n \times \text{Empirical Formula}

Concentration Interconversions

M=1000×d×w%Mr×100M = \frac{1000 \times d \times w\%}{M_r \times 100}

m=1000×w%Mr×(100w%)m = \frac{1000 \times w\%}{M_r \times (100 - w\%)}

N=M×n-factorN = M \times n\text{-factor}

Equivalent weight=Mrn-factor\text{Equivalent weight} = \frac{M_r}{n\text{-factor}}

Key Reactions with Conditions

Na2CO3Na_{2}CO_{3} + 2 HCl → 2 NaCl + H2OH_{2}O + CO2CO_{2} (aq, room temp)

CaCO3CaCO_{3} --[heat, >840 °C]--> CaO + CO2CO_{2}

2 H2H_{2} + O2O_{2} --[spark / Pt catalyst]--> 2 H2OH_{2}O

H_{2}$$SO_{4} + 2 NaOH → Na_{2}$$SO_{4} + 2 H2OH_{2}O (neutralisation, aq)

Limiting Reagent Method

  1. Convert all given masses to moles using molar masses.
  2. Divide each by its stoichiometric coefficient.
  3. The reactant with the smallest such value is the limiting reagent.
  4. Theoretical yield = moles of limiting reagent × stoichiometric ratio to product × molar mass of product.

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