Part of JPC-03 — Electrochemistry: Nernst, Conductance & Cells

Faraday's Laws of Electrolysis

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First Law: mass deposited is proportional to charge passed. m = ZIt = MItnF\frac{MIt}{nF}. Z = MnF\frac{M}{nF} is the electrochemical equivalent. Second Law: for same charge through different electrolytes, masses deposited are proportional to equivalent weights Mn\frac{M}{n}. 1 Faraday (F) = 96485 C = charge carried by 1 mole of electrons. 1 F deposits: 108 g Ag (n=1), 31.75 g Cu (n=2), 9 g Al (n=3). Charge Q = It (current x time). Always convert time to seconds. For series electrolytic cells (same current), compare masses using equivalent weights. For parallel cells (same voltage), currents may differ.

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