s-Block Position
The s-block occupies the left two columns of the periodic table (Groups 1 and 2) plus helium (He, 1):
Period 1: H (1$s^{1}$) .......... He (1$s^{2}$) [noble gas]
Period 2: Li (2$s^{1}$), Be (2$s^{2}$)
Period 3: Na (3$s^{1}$), Mg (3$s^{2}$)
Period 4: K (4$s^{1}$), Ca (4$s^{2}$)
Period 5: Rb (5$s^{1}$), Sr (5$s^{2}$)
Period 6: Cs (6$s^{1}$), Ba (6$s^{2}$)
Period 7: Fr (7$s^{1}$), Ra (7$s^{2}$)
Key trends across a period (Group 1 → Group 2):
- Atomic radius: ↓ decreases (more nuclear charge, same shell)
- Ionization enthalpy: ↑ increases (Group 2 > Group 1 in same period)
- Melting point: ↑ increases (Group 2 has stronger metallic bonds from 2 valence electrons)
Why Group 2 has smaller radius than Group 1 in same period: Going from Na (Group 1, [Ne]3) to Mg (Group 2, [Ne]3): +1 proton pulls electrons in → smaller radius despite more electrons.