Part of JINC-01 — Coordination Compounds: Nomenclature, Isomerism & CFT

Crystal Field Theory — Tetrahedral Splitting

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In tetrahedral geometry, ligands approach between the axes (along cube diagonals). Now dxy, dyz, dxz point closer to ligands — they go UP in energy forming the t2 set. dx2-y2 and dz2 are stabilised, forming the e set. The splitting is inverted compared to octahedral. DeltatetDelta_{tet} = 49\frac{4}{9} DeltaoctDelta_{oct} because: (1) only 4 ligands instead of 6, and (2) ligands don't point directly at any orbital. Because DeltatetDelta_{tet} is small, tetrahedral complexes are almost always high spin. Tetrahedral complexes never show the kind of low-spin behaviour common in octahedral complexes. Pairing energy almost always exceeds DeltatetDelta_{tet}.

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