In tetrahedral geometry, ligands approach between the axes (along cube diagonals). Now dxy, dyz, dxz point closer to ligands — they go UP in energy forming the t2 set. dx2-y2 and dz2 are stabilised, forming the e set. The splitting is inverted compared to octahedral. = because: (1) only 4 ligands instead of 6, and (2) ligands don't point directly at any orbital. Because is small, tetrahedral complexes are almost always high spin. Tetrahedral complexes never show the kind of low-spin behaviour common in octahedral complexes. Pairing energy almost always exceeds .
Part of JINC-01 — Coordination Compounds: Nomenclature, Isomerism & CFT
Crystal Field Theory — Tetrahedral Splitting
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