In tetrahedral geometry, ligands approach between the axes (along cube diagonals). Now dxy, dyz, dxz point closer to ligands — they go UP in energy forming the t2 set. dx2-y2 and dz2 are stabilised, forming the e set. The splitting is inverted compared to octahedral. Delta_tet = (4/9) Delta_oct because: (1) only 4 ligands instead of 6, and (2) ligands don't point directly at any orbital. Because Delta_tet is small, tetrahedral complexes are almost always high spin. Tetrahedral complexes never show the kind of low-spin behaviour common in octahedral complexes. Pairing energy almost always exceeds Delta_tet.
Part of JINC-01 — Coordination Compounds: Nomenclature, Isomerism & CFT
Crystal Field Theory — Tetrahedral Splitting
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