| Feature | Reversible Isothermal | Irreversible (Const. ) | Free Expansion |
|---|---|---|---|
| Work formula | $0$ | ||
| Heat | (for isothermal ideal gas) | $0$ | |
| $0$ (ideal gas, isothermal) | $0$ (ideal gas, isothermal) | $0$ (ideal gas) | |
| $0$ | |||
| Work magnitude | Maximum | Intermediate | Zero |
| Realizability | Theoretical limit | Real processes | Real (into vacuum) |
| Spontaneous? | Borderline (reversible) | Yes | Yes |
Key insight: is the same for all three (state function), but differentiates reversible from irreversible.