Part of PC-06 — Equilibrium: Chemical & Ionic

Comparison Note — Acid-Base Theories

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FeatureArrheniusBronsted-LowryLewis
Acid defined asProduces H+H^{+} in waterProton (H+H^{+}) donorElectron pair acceptor
Base defined asProduces OHOH^{-} in waterProton (H+H^{+}) acceptorElectron pair donor
Medium requiredAqueous onlyAny solventAny medium (no solvent needed)
Explains BF3BF_{3} + NH3NH_{3}?NoNo (no proton transfer)Yes — BF3BF_{3} accepts ee^{-} pair from NH3NH_{3}
Explains NH3NH_{3} + HCl?PartiallyYes — NH3NH_{3} accepts H+H^{+}Yes
Conjugate pairs?Not definedYes (HA / AA^{-}; BH+H^{+} / B)Not applicable
ScopeNarrowestIntermediateBroadest
NEET frequencyLow (definition Qs)High (conjugate pair, Ka × Kb)Moderate (Lewis acid examples)
Key limitationOnly aqueous; cannot explain NH3NH_{3} as base without OHOH^{-}Cannot explain non-proton transfer acid-base (e.g., CO2CO_{2} + CaO)So broad that even simple cation-anion interactions qualify
Example acidsHCl, H2SO4H_{2}SO_{4}HCl, H2OH_{2}O (as acid)BF3BF_{3}, AlCl3AlCl_{3}, Fe3+Fe^{3+}
Example basesNaOH, KOHNH3NH_{3}, H2OH_{2}O (as base)NH3NH_{3}, FF^{-}, OHOH^{-}

Key NEET fact: Ka × Kb = Kw = 10^{-14} at 25°C for any conjugate acid-base pair (Bronsted-Lowry framework).

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