Part of INC-02 — p-Block Elements: Groups 13-15

Common Misconceptions — INC-02

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M1: "H3BO3H_{3}BO_{3} has 3 acidic H atoms." CORRECT: H3BO3H_{3}BO_{3} is monobasic. Only 1 H+H^{+} is released per molecule via Lewis acid mechanism.

M2: "Boric acid donates protons just like HCl." CORRECT: H3BO3H_{3}BO_{3} is a Lewis acid (accepts OHOH^{-}), not a Bronsted acid (H+H^{+} donor).

M3: "H3PO3H_{3}PO_{3} is tribasic because it has 3 H atoms." CORRECT: H3PO3H_{3}PO_{3} is DIBASIC (2 P-OH bonds). Total H count ≠ basicity.

M4: "Black phosphorus is rare and unimportant." CORRECT: Black P is the most thermodynamically stable allotrope. It is also a layered semiconductor, researched extensively for transistors.

M5: "The Haber process uses Pt catalyst." CORRECT: Haber process uses finely divided Fe. Pt/Rh is used in Ostwald Step 1.

M6: "All steps of the Ostwald process need a catalyst." CORRECT: Only Step 1 (NH3NH_{3} oxidation) needs Pt-Rh. Step 2 and Step 3 are uncatalysed.

M7: "N2O3N_{2}O_{3} and NO2NO_{2} are neutral oxides." CORRECT: Both are acidic. Only N2ON_{2}O and NO are neutral nitrogen oxides.

M8: "NO2NO_{2} is diamagnetic." CORRECT: NO2NO_{2} has 17 electrons (odd) — it is paramagnetic with 1 unpaired electron.

M9: "Diborane has a B-B bond." CORRECT: There is NO direct B-B bond in B2H6B_{2}H_{6}. The two B atoms are linked only through the two bridging H atoms (via 3c-2e bonds).

M10: "In PCl5PCl_{5}, all bonds are equal in length." CORRECT: Axial P-Cl bonds (~214 pm) are longer than equatorial P-Cl bonds (~202 pm) due to greater 90° repulsion on axial bonds.

M11: "NCl5NCl_{5} exists like PCl5PCl_{5}." CORRECT: NCl5NCl_{5} cannot exist because N has no d-orbitals in its valence shell (n=2) for sp3sp^{3}d hybridization. P has 3d orbitals available.

M12: "AlCl3AlCl_{3} is a simple monomer in all conditions." CORRECT: AlCl3AlCl_{3} exists as dimer Al2Cl6Al_{2}Cl_{6} in solid state and in non-polar solvents, though it dissociates to monomer in polar solvents and at very high temperatures in gas phase.

M13: "High pressure is not commercially feasible for Haber — so low pressure is used." CORRECT: Approximately 200 atm IS used in the Haber process. This is commercially viable with modern engineering.

M14: "White phosphorus is stored in air under controlled conditions." CORRECT: White P must be stored under water (not air), because it ignites spontaneously in air.

M15: "CO2CO_{2} fire extinguishers work on all types of fires including metal fires." CORRECT: CO2CO_{2} extinguishers must NEVER be used on Mg fires. Burning Mg reduces CO2CO_{2} (2Mg + CO2CO_{2} → 2MgO + C), potentially spreading the fire.

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