Colour arises from d-d transitions — absorption of visible light promotes an electron from lower to higher d-orbital. Requirements: partially filled d-orbitals (at least one electron AND at least one vacancy). Therefore (, ) and (, ) ions are colourless. Typical colours of aqueous ions: (purple), (green), (green), (very pale pink), (green), (yellow-brown), (pink), (green), (blue). is nearly colourless because high spin has all transitions spin-forbidden.
Part of JINC-02 — d-Block & f-Block Elements
Colour of Transition Metal Ions
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