Part of JINC-02 — d-Block & f-Block Elements

Colour of Transition Metal Ions

by Notetube Official71 words8 views

Colour arises from d-d transitions — absorption of visible light promotes an electron from lower to higher d-orbital. Requirements: partially filled d-orbitals (at least one electron AND at least one vacancy). Therefore d0d^0 (Sc3+Sc^{3+}, Ti4+Ti^{4+}) and d10d^{10} (Cu+Cu^+, Zn2+Zn^{2+}) ions are colourless. Typical colours of aqueous M2+M^{2+} ions: Ti3+Ti^{3+}(purple), V3+V^{3+}(green), Cr3+Cr^{3+}(green), Mn2+Mn^{2+}(very pale pink), Fe2+Fe^{2+}(green), Fe3+Fe^{3+}(yellow-brown), Co2+Co^{2+}(pink), Ni2+Ni^{2+}(green), Cu2+Cu^{2+}(blue). Mn2+Mn^{2+} is nearly colourless because d5d^5 high spin has all transitions spin-forbidden.

Like these notes? Save your own copy and start studying with NoteTube's AI tools.

Sign up free to clone these notes