Part of JINC-04 — s-Block Elements & Hydrogen

Alkali Metals — General Trends

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Group 1: Li, Na, K, Rb, Cs, Fr. Configuration [noble gas] ns1ns^1. Trends down the group: Atomic radius increases, IE decreases (520 → 376 kJ/mol), electronegativity decreases, metallic character increases, reactivity with water increases. All are strong reducing agents (large negative E0E^0 values). Electrode potentials: Li has the most negative E0E^0 (-3.04 V), making it the strongest reducing agent in aqueous solution despite having the highest IE — because Li+Li^+ has very high hydration energy (small ion, strong ion-dipole interactions). Flame test works because thermal energy promotes ns1ns^1 electron; the emitted photon on de-excitation has visible wavelength. All alkali metals are stored under kerosene (react with air and moisture).

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