Part of INC-02 — p-Block Elements: Groups 13-15

7-Step Reasoning: Why Is H₃BO₃ a Lewis Acid?

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Step 1 — Electronic Structure of Boron: Boron has atomic number 5, configuration 1s2s^{2} 2s2s^{2} 2p1p^{1}. In compounds, it typically uses sp2sp^{2} hybridization, contributing 3 electrons to 3 bonds.

Step 2 — Electron Count in H3BO3H_{3}BO_{3}: In H3BO3H_{3}BO_{3}, boron forms 3 bonds to oxygen (sp2sp^{2} hybridized). This gives B only 6 electrons around it (3 bonding pairs × 2 electrons = 6), NOT 8. Boron is therefore electron-deficient — it lacks a complete octet.

Step 3 — What Does an Electron-Deficient Atom Want? An electron-deficient atom is an electron-pair acceptor by definition. This is precisely the definition of a Lewis acid.

Step 4 — How Does H3BO3H_{3}BO_{3} React with Water? Water (H2OH_{2}O) has lone pairs on oxygen. When H3BO3H_{3}BO_{3} encounters water, the electron-deficient B accepts a lone pair from one O of H2OH_{2}O (acting as Lewis base), forming a new B-O coordinate bond: H3BO3H_{3}BO_{3} + H2OH_{2}O → [B(OH)_{4}]^{-} + H+H^{+}

Step 5 — Why Is the Proton Released? When B accepts OHOH^{-} from water, the water molecule loses OHOH^{-} and releases H+H^{+} into solution. The H+H^{+} comes from WATER, not from H3BO3H_{3}BO_{3}.

Step 6 — Why Monobasic, Not Tribasic? Despite three OH groups in H3BO3H_{3}BO_{3}, only ONE H+H^{+} is released per molecule (only one B-OH addition occurs per B centre). Boron becomes tetrahedral [B(OH)_{4}]^{-} after accepting one OHOH^{-} — it is now satisfied (8 electrons) and no further reaction occurs.

Step 7 — Conclusion: H3BO3H_{3}BO_{3} is a LEWIS acid (electron-pair acceptor), NOT a Bronsted acid (H+H^{+} donor). Its acidity arises from boron's electron deficiency, not from O-H bond polarity. It is monobasic because only one H+H^{+} is produced per molecule.

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