Step 1 — Electronic Structure of Boron: Boron has atomic number 5, configuration 1 2 2. In compounds, it typically uses hybridization, contributing 3 electrons to 3 bonds.
Step 2 — Electron Count in : In , boron forms 3 bonds to oxygen ( hybridized). This gives B only 6 electrons around it (3 bonding pairs × 2 electrons = 6), NOT 8. Boron is therefore electron-deficient — it lacks a complete octet.
Step 3 — What Does an Electron-Deficient Atom Want? An electron-deficient atom is an electron-pair acceptor by definition. This is precisely the definition of a Lewis acid.
Step 4 — How Does React with Water? Water () has lone pairs on oxygen. When encounters water, the electron-deficient B accepts a lone pair from one O of (acting as Lewis base), forming a new B-O coordinate bond: + → [B(OH)_{4}]^{-} +
Step 5 — Why Is the Proton Released? When B accepts from water, the water molecule loses and releases into solution. The comes from WATER, not from .
Step 6 — Why Monobasic, Not Tribasic? Despite three OH groups in , only ONE is released per molecule (only one B-OH addition occurs per B centre). Boron becomes tetrahedral [B(OH)_{4}]^{-} after accepting one — it is now satisfied (8 electrons) and no further reaction occurs.
Step 7 — Conclusion: is a LEWIS acid (electron-pair acceptor), NOT a Bronsted acid ( donor). Its acidity arises from boron's electron deficiency, not from O-H bond polarity. It is monobasic because only one is produced per molecule.